論文

査読有り
2011年9月

Structural Origin of the Antimagic Number in Protonated Water Clusters H+(H2O)(n): Spectroscopic Observation of the "Missing" Water Molecule in the Outermost Hydration Shell

JOURNAL OF PHYSICAL CHEMISTRY LETTERS
  • Kenta Mizuse
  • ,
  • Asuka Fuji

2
17
開始ページ
2130
終了ページ
2134
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/jz200996q
出版者・発行元
AMER CHEMICAL SOC

To investigate the origin of the instability of the water network consisting of a specific (so-called antimagic) number of molecules, we report infrared spectra of cold protonated water clusters H+(H2O)(n) (n = 20-23) tagged with weakly bound H-2 molecules. In this size range, only in n = 22, which has been known to be an antimagic number cluster, is a band attributed to the one-coordinated, dangling water molecule observed. This observation indicates that the 22nd water molecule is loosely bound to the surface of the closed cage structure of H+(H2O)(21). This band has been missing in any spectra of the warmer and bare cluster of n = 22. The present results evidence the characteristic cluster structure of the antimagic numbered cluster, which has been predicted by Singh et al. (Angew. Chem., Int. Ed, 2006, 45, 3795) and suggests that the thermal and dynamic effects perturb the spectrum, structure, or both in warmer cases.

リンク情報
DOI
https://doi.org/10.1021/jz200996q
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000294701800010&DestApp=WOS_CPL
ID情報
  • DOI : 10.1021/jz200996q
  • ISSN : 1948-7185
  • Web of Science ID : WOS:000294701800010

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