論文

査読有り 招待有り 本文へのリンクあり
2009年10月

Precise elemental and isotopic analyses in silicate samples employing ICP-MS: Application of hydrofluoric acid solution and analytical techniques

Analytical Sciences
  • Akio Makishima
  • ,
  • Ryoji Tanaka
  • ,
  • Eizo Nakamura

25
10
開始ページ
1181
終了ページ
1187
記述言語
英語
掲載種別
DOI
10.2116/analsci.25.1181
出版者・発行元
JAPAN SOC ANALYTICAL CHEMISTRY

In this review, a new classification of elements based on behavior in hydrofluoric acid (HF) solution is presented for the precise quantitative analysis of each element by inductively coupled plasma mass spectrometry (ICP-MS). The elements are divided into 7 groups: (1) "fluorophile" elements; (2) insoluble fluoride-forming elements; (3) "bromophile" or "iodophile" elements; (4) "oxophile" elements; (5) "aquaphile" elements; (6) bare cation elements; and (7) other elements. Especially, the importance of fluorophile and insoluble fluoride-forming elements in elemental analysis is described. Due to the elemental characteristics, these two groups of elements cannot be dissolved simultaneously in the same solution, and thus cannot be measured together. In addition, coprecipitation of the fluorophile elements with the insoluble fluorides occurs in some conditions and hinders accurate analysis. The peculiar conditions when the coprecipitation occurs are discussed, and the "Al-addition" and "Mg-addition" methods for overcoming these problems are described. In addition, some state-of-the-art analytical techniques in ICP-MS are shown, and future directions of the element analysis are presented.

リンク情報
DOI
https://doi.org/10.2116/analsci.25.1181
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000277212700002&DestApp=WOS_CPL
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=72249116718&origin=inward 本文へのリンクあり
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=72249116718&origin=inward
ID情報
  • DOI : 10.2116/analsci.25.1181
  • ISSN : 0910-6340
  • eISSN : 1348-2246
  • SCOPUS ID : 72249116718
  • Web of Science ID : WOS:000277212700002

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