2002年9月15日
High precision measurement of titanium isotope ratios by plasma source mass spectrometry
International Journal of Mass Spectrometry
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- 巻
- 220
- 号
- 1
- 開始ページ
- 21
- 終了ページ
- 29
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/S1387-3806(02)00767-4
A method using multiple-collector inductively coupled plasma source mass spectrometry for the precise measurement of Ti isotope composition in natural materials has been developed. Instrumental mass discrimination is corrected using a "standard-sample bracketing" approach by expressing the isotope ratios of samples relative to those of the bracketing standard. Variations in 47Ti/46Ti, 48Ti/46Ti, 49Ti/46Ti and 50Ti/46Ti ratios of samples are expressed in ε units which are deviations in parts per 104 from the same isotope ratios of the reference material. The long-term repeatability at the 2 standard deviation level is 0.4, 0.6, 0.7 and 0.8 ε units in terms of 47Ti/46Ti, 48Ti/46Ti, 49Ti/46Ti and 50Ti/46Ti ratio measurements, respectively. The technique reported here makes it possible for the first time that both mass-dependent fractionation and isotope anomalies of Ti isotopes in natural materials can be measured to high precision. © 2002 Elsevier Science B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/S1387-3806(02)00767-4
- ISSN : 1387-3806
- SCOPUS ID : 0037105339