論文

1995年10月

Molecular recognition: New chiral metalloporphyrins as receptor models

Supramolecular Chemistry
  • Hisanobu Ogoshi
  • ,
  • Tadashi Ema
  • ,
  • Yusuke Kato
  • ,
  • Tadashi Mizutani
  • ,
  • Yasuhisa Kuroda

6
1-2
開始ページ
115
終了ページ
124
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1080/10610279508032527

New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest. © 1995, Taylor & Francis Group, LLC. All rights reserved.

リンク情報
DOI
https://doi.org/10.1080/10610279508032527
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=0000885625&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=0000885625&origin=inward
ID情報
  • DOI : 10.1080/10610279508032527
  • ISSN : 1061-0278
  • eISSN : 1029-0478
  • SCOPUS ID : 0000885625

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