1995年10月
Molecular recognition: New chiral metalloporphyrins as receptor models
Supramolecular Chemistry
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- ,
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- 巻
- 6
- 号
- 1-2
- 開始ページ
- 115
- 終了ページ
- 124
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1080/10610279508032527
New chiral metalloporphyrins capable of multi-point recognition are prepared and their recognition behavior, especially chiral recognition, is studied. The first part of the paper is concerned with general formalism for multi-point recognition, where uniqueness of multi-point recognition, isolation of interaction in terms of free energy, enthalpy and entropy, and the meaning of these thermodynamic parameters are discussed. Enantioselective binding of amino acid esters to two new chiral porphyrins is investigated by UV-vis, NMR and IR spectroscopic methods. Chiral recognition is achieved by combination of three recognition interactions between host and guest. © 1995, Taylor & Francis Group, LLC. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1080/10610279508032527
- ISSN : 1061-0278
- eISSN : 1029-0478
- SCOPUS ID : 0000885625