2015年1月
STEREOSELECTIVE SYNTHESIS OF THE A-RING OF ARMATOL A FROM A BROMO-SUBSTITUTED CHIRAL BUILDING BLOCK BASED ON IRELAND-CLAISEN REARRANGEMENT AND RING-CLOSING OLEFIN METATHESIS
HETEROCYCLES
- ,
- ,
- ,
- ,
- 巻
- 91
- 号
- 1
- 開始ページ
- 76
- 終了ページ
- 103
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.3987/COM-14-13143
- 出版者・発行元
- PERGAMON-ELSEVIER SCIENCE LTD
The stereoselective synthesis of the A-ring of armatol A, a natural polycyclic ether triterpene from the red alga Chondria armata, was achieved in a non-biomimetic way. The synthesis employed Ireland-Claisen rearrangement of an ester, prepared from a bromo-substituted chiral building block, for the construction of C6 and C7 stereocenters and a relay ring-closing olefin metathesis for the seven-membered ring formation.
- リンク情報
- ID情報
-
- DOI : 10.3987/COM-14-13143
- ISSN : 0385-5414
- eISSN : 1881-0942
- ORCIDのPut Code : 20511210
- Web of Science ID : WOS:000352046900005