Sodium manganese orthosilicate, Na2MnSiO4, was synthesized by a sol-gel method and investigated for use as a positive electrode material for Na secondary batteries using Na[FSA]-[C(3)C(1)pyrr][FSA] (FSA = bis(fluorosulfonyl) amide anion and C(3)C(1)pyrr = N-methyl-N-propylpyrrolidinium cation) ionic liquid electrolyte in the temperature range 298-363 K. Carbon coating and elevation of operational temperatures significantly improved the electrode performance. A reversible capacity of 125 mAh g(-1) (90% of the theoretical value based on a one-electron transfer process) was found at a rate of C/10 (13.9 mA g(-1)) within 2.0-4.0 V at 363 K, with an acceptably high rate capability. Na2MnSiO4 became amorphous upon the electrochemical removal of sodium, exhibiting a similar behavior as its lithium equivalent. Both Na2MnSiO4 and its desodiated form (Na0.8MnSiO4) possess remarkable thermal stability, suggesting their safety characteristic. (C) 2014 Elsevier B.V. All rights reserved.