2006年1月
Fluorination with ionic liquid EMIMF(HF)(2.3) as mild HF source
JOURNAL OF FLUORINE CHEMISTRY
- ,
- ,
- ,
- ,
- ,
- 巻
- 127
- 号
- 1
- 開始ページ
- 29
- 終了ページ
- 35
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.jfluchem.2005.09.016
- 出版者・発行元
- ELSEVIER SCIENCE SA
Hydrogen fluoride is a basic fluorinating reagent, but handling it is difficult. For this reason, some modified fluorinating reagents such as HF-pyridine, Et3N-HF, and poly(hydrogen fluoride) complex have been developed. Those reagents, however, still require aqueous work-up procedures which generate hydrogen fluoride. Recently, ionic liquids have received much attention because of the ease in handling them and the possibility of non-aqueous work-up. An ionic liquid, 3-ethyl-1-methyimidazolium oligo hydrogen fluoride (EM1MF(HF)(2.3)), which is stable in air and moisture, can be used as a hydrogen fluoride equivalent for some fluorination reactions; it does not require an aqueous work-up. (C) 2005 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
-
- DOI : 10.1016/j.jfluchem.2005.09.016
- ISSN : 0022-1139
- ORCIDのPut Code : 48252195
- Web of Science ID : WOS:000234532600005