論文

査読有り
2006年1月

Fluorination with ionic liquid EMIMF(HF)(2.3) as mild HF source

JOURNAL OF FLUORINE CHEMISTRY
  • H Yoshino
  • ,
  • K Matsumoto
  • ,
  • R Hagiwara
  • ,
  • Y Ito
  • ,
  • K Oshima
  • ,
  • S Matsubara

127
1
開始ページ
29
終了ページ
35
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.jfluchem.2005.09.016
出版者・発行元
ELSEVIER SCIENCE SA

Hydrogen fluoride is a basic fluorinating reagent, but handling it is difficult. For this reason, some modified fluorinating reagents such as HF-pyridine, Et3N-HF, and poly(hydrogen fluoride) complex have been developed. Those reagents, however, still require aqueous work-up procedures which generate hydrogen fluoride. Recently, ionic liquids have received much attention because of the ease in handling them and the possibility of non-aqueous work-up. An ionic liquid, 3-ethyl-1-methyimidazolium oligo hydrogen fluoride (EM1MF(HF)(2.3)), which is stable in air and moisture, can be used as a hydrogen fluoride equivalent for some fluorination reactions; it does not require an aqueous work-up. (C) 2005 Elsevier B.V. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.jfluchem.2005.09.016
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000234532600005&DestApp=WOS_CPL
URL
http://orcid.org/0000-0002-0770-9210
ID情報
  • DOI : 10.1016/j.jfluchem.2005.09.016
  • ISSN : 0022-1139
  • ORCIDのPut Code : 48252195
  • Web of Science ID : WOS:000234532600005

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