論文

査読有り
2014年10月

Introduction of an Ionic Liquid into the Micropores of a Metal-Organic Framework and Its Anomalous Phase Behavior

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
  • Kazuyuki Fujie
  • ,
  • Teppei Yamada
  • ,
  • Ryuichi Ikeda
  • ,
  • Hiroshi Kitagawa

53
42
開始ページ
11302
終了ページ
11305
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/anie.201406011
出版者・発行元
WILEY-V C H VERLAG GMBH

Controlling the dynamics of ionic liquids (ILs) is a significant issue for widespread use. Metal-organic frameworks (MOFs) are ideal host materials for ILs because of their small micropores and tunable host-guest interactions. Herein, we demonstrate the first example of an IL incorporated within the micropores of a MOF. The system studied consisted of EMI-TFSA (1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide) and ZIF-8 (composed of Zn(MeIM)(2); H(MeIM)=2-methylimidazole) as the IL and MOF, respectively. Construction of the EMI-TFSA in ZIF-8 was confirmed by X-ray powder diffraction, nitrogen gas adsorption, and infrared absorption spectroscopy. Differential scanning calorimetry and solid-state NMR measurements showed that the EMI-TFSA inside the micropores demonstrated no freezing transition down to 123K, whereas bulk EMI-TFSA froze at 231K. Such anomalous phase behavior originates from the nanosize effect of the MOF on the IL. This result provides a novel strategy for stabilizing the liquid phase of the ILs down to a lower temperature region.

リンク情報
DOI
https://doi.org/10.1002/anie.201406011
J-GLOBAL
https://jglobal.jst.go.jp/detail?JGLOBAL_ID=201402200149489526
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/25167856
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000343751100035&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/anie.201406011
  • ISSN : 1433-7851
  • eISSN : 1521-3773
  • J-Global ID : 201402200149489526
  • PubMed ID : 25167856
  • Web of Science ID : WOS:000343751100035

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