2017年4月
Solid-Solution Alloying of Immiscible Ru and Cu with Enhanced CO Oxidation Activity
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
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- 巻
- 139
- 号
- 13
- 開始ページ
- 4643
- 終了ページ
- 4646
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jacs.7b01186
- 出版者・発行元
- AMER CHEMICAL SOC
We report on novel solid-solution alloy nanoparticles (NPs) of Ru and Cu that are completely immiscible even above melting point in bulk phase. Powder X-ray diffraction, scanning transmission electron microscopy, and energy-dispersive X-ray measurements demonstrated that Ru and Cu atoms were homogeneously distributed in the alloy NPs. Ru0.5Cu0.5 NPs demonstrated higher CO oxidation activity than fcc-Ru NPs, which are known as one of the best monometallic CO oxidation catalysts.
- リンク情報
- ID情報
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- DOI : 10.1021/jacs.7b01186
- ISSN : 0002-7863
- PubMed ID : 28338315
- Web of Science ID : WOS:000398764000010