論文

査読有り
2017年8月

The Concentration Control of Magnetic Fullerene C-60(center dot-) Radical Anions in a Crystal Lattice of the (Bu4N+)(2){(C-60(center dot-))C6H4Cl2}(x){[CpMo(CO)(2)C-60](-)}(2-x) (x=1, 0.74) Complexes

CHEMISTRYSELECT
  • Dmitri V. Konarev
  • ,
  • Salavat S. Khasanov
  • ,
  • Sergey I. Troyanov
  • ,
  • Akihiro Otsuka
  • ,
  • Hideki Yamochi
  • ,
  • Hiroshi Kitagawa
  • ,
  • Rimma N. Lyubovskaya

2
23
開始ページ
6640
終了ページ
6644
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/slct.201701083
出版者・発行元
WILEY-V C H VERLAG GMBH

Interaction of the (Bu4N+)(C-60(center dot-)) salt with {CpMo(CO)(3)}(2) at a different molar ratio allows one to obtain isostructural (Bu4N+)(2){(C-60(center dot-))C6H4Cl2}(x){[CpMo(CO)(2)C-60](-)}(2-x) complexes with x=1 (1) and 0.74 (2). The complexes contain the solvated C-60(center dot-) radical anions and the coordination [CpMo(CO)(2)C-60](-) anions which share one position in the crystal structure with different occupancies. Molybdenum atom coordinates by the eta(2)-type to the 6-6 bond of C-60 in the [CpMo(CO)(2)(eta(2)-C-60)](-) anions. The length of the Mo-C(C-60) bonds is 2.241(6)-2.244(6) angstrom. Optical spectrum of 1 supports the presence of uncoordinated C-60(center dot-) and neutral coordinated C-60 in [CpMo(CO)(2)(eta(2)-C-60)](-). Paramagnetism of C-60(center dot-) in 1 provides effective magnetic moment of 1.2 mu(B) whereas coordination [CpMo(CO)(2)(eta(2)-C-60)](-) anions are diamagnetic and EPR silent. Fullerenes form closely packed double ribbons with triangular fullerene lattice. 1 shows antiferromagnetic coupling of spins with a small Weiss temperature of -7K. That can be explained by magnetic dilution of paramagnetic C-60 center dot- species by diamagnetic [CpMo(CO)(2)(eta(2)-C-60)](-) anions.

リンク情報
DOI
https://doi.org/10.1002/slct.201701083
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000408044100005&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/slct.201701083
  • ISSN : 2365-6549
  • Web of Science ID : WOS:000408044100005

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