2017年8月
The Concentration Control of Magnetic Fullerene C-60(center dot-) Radical Anions in a Crystal Lattice of the (Bu4N+)(2){(C-60(center dot-))C6H4Cl2}(x){[CpMo(CO)(2)C-60](-)}(2-x) (x=1, 0.74) Complexes
CHEMISTRYSELECT
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- 巻
- 2
- 号
- 23
- 開始ページ
- 6640
- 終了ページ
- 6644
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/slct.201701083
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Interaction of the (Bu4N+)(C-60(center dot-)) salt with {CpMo(CO)(3)}(2) at a different molar ratio allows one to obtain isostructural (Bu4N+)(2){(C-60(center dot-))C6H4Cl2}(x){[CpMo(CO)(2)C-60](-)}(2-x) complexes with x=1 (1) and 0.74 (2). The complexes contain the solvated C-60(center dot-) radical anions and the coordination [CpMo(CO)(2)C-60](-) anions which share one position in the crystal structure with different occupancies. Molybdenum atom coordinates by the eta(2)-type to the 6-6 bond of C-60 in the [CpMo(CO)(2)(eta(2)-C-60)](-) anions. The length of the Mo-C(C-60) bonds is 2.241(6)-2.244(6) angstrom. Optical spectrum of 1 supports the presence of uncoordinated C-60(center dot-) and neutral coordinated C-60 in [CpMo(CO)(2)(eta(2)-C-60)](-). Paramagnetism of C-60(center dot-) in 1 provides effective magnetic moment of 1.2 mu(B) whereas coordination [CpMo(CO)(2)(eta(2)-C-60)](-) anions are diamagnetic and EPR silent. Fullerenes form closely packed double ribbons with triangular fullerene lattice. 1 shows antiferromagnetic coupling of spins with a small Weiss temperature of -7K. That can be explained by magnetic dilution of paramagnetic C-60 center dot- species by diamagnetic [CpMo(CO)(2)(eta(2)-C-60)](-) anions.
- リンク情報
- ID情報
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- DOI : 10.1002/slct.201701083
- ISSN : 2365-6549
- Web of Science ID : WOS:000408044100005