2020年5月13日
Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR.
Physical chemistry chemical physics : PCCP
- ,
- ,
- ,
- ,
- ,
- ,
- ,
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1039/d0cp01216e
The application of high-resolution NMR analysis for CO2 adsorbed in a MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had an unusually slow mobility (τ ∼ 10-8 s). CO2-CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at the adsorption sites.
- ID情報
-
- DOI : 10.1039/d0cp01216e
- PubMed ID : 32400799