論文

査読有り
2020年6月19日

Recent Progress on Catalytic Addition Reactions to N-Unsubstituted Imines

ACS Catalysis
  • Hiroyuki Morimoto

10
12
開始ページ
6924
終了ページ
6951
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acscatal.0c01212

© 2020 American Chemical Society. Catalytic addition reactions to N-unsubstituted (N-unprotected) imines can provide a more straightforward synthesis of amines. This direct process eliminates the unnecessary protecting-group manipulations that are required with N-substituted (N-protected) imines and can contribute to the development of green chemistry. Although their use has been limited due to difficulties associated with the nature of N-unsubstituted imines, recently developed catalytic methods enable the use of N-unsubstituted imines as electrophiles in various catalytic addition reactions. To facilitate an understanding of the state of the art development of synthetic methodologies, herein we review recent progress on catalytic addition reactions to N-unsubstituted imines. We begin with an overview of the chemistry of N-unsubstituted imines, followed by a summary of recent progress categorized according to the reaction type. We hope this review will help to stimulate further development of greener syntheses of nitrogen-containing compounds.

リンク情報
DOI
https://doi.org/10.1021/acscatal.0c01212
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85087823031&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85087823031&origin=inward
ID情報
  • DOI : 10.1021/acscatal.0c01212
  • ISSN : 2155-5435
  • eISSN : 2155-5435
  • ORCIDのPut Code : 76291560
  • SCOPUS ID : 85087823031

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