2020年4月
Hydrogen-bonded porous frameworks constructed by rigid pi-conjugated molecules with carboxy groups
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
- 巻
- 96
- 号
- 3-4
- 開始ページ
- 215
- 終了ページ
- 231
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1007/s10847-019-00972-0
- 出版者・発行元
- SPRINGER
This review covers construction and properties of porous molecular crystals (PMCs) constructed through hydrogen-bonding of C-3-symmetric, rigid, pi-conjugated molecular building blocks possessing carboxyaryl groups, which was reported in the last 5 years by the author's group. PMCs with well-defined, self-standing pores have been attracted attention due to various functionalities provided by selective and reversible inclusion of certain chemical species into the pores. However, it has been recognized for long time that construction of PMCs with permanent porosity is not easy due to weakness of noncovalent intermolecular interactions. Systematic construction of PMCs have been limited so far. To overcome this problem, the author has proposed a unique molecular design concept based on C-3-symmetric pi-conjugated molecules (C(3)PIs) possessing o-bis(4-carboxyphenyl)benzene moieties in their periphery and demonstrated that C(3)PIs systematically yielded hydrogen-bonded organic frameworks (HOFs) composed of H-bonded 2D hexagonal networks (H-HexNets) or interpenetrated 3D pcu-networks, which exhibit permanent porosity, significant thermal stability, polar solvent durability, robustness/flexibility, and/or multifunctionality.
- リンク情報
-
- DOI
- https://doi.org/10.1007/s10847-019-00972-0
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000520848700002&DestApp=WOS_CPL
- URL
- http://link.springer.com/content/pdf/10.1007/s10847-019-00972-0.pdf
- URL
- http://link.springer.com/article/10.1007/s10847-019-00972-0/fulltext.html
- ID情報
-
- DOI : 10.1007/s10847-019-00972-0
- ISSN : 1388-3127
- eISSN : 1573-1111
- Web of Science ID : WOS:000520848700002