論文

査読有り
2021年6月

Stereoselective Enhancement of VCD Signals for Intercalation Compounds of Sodium Montmorillonite and Chiral Metal Complexes

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
  • Hisako Sato
  • ,
  • Kazuyoshi Takimoto
  • ,
  • Jun Yoshida
  • ,
  • Akihiko Yamagishi

94
6
開始ページ
1731
終了ページ
1736
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/bcsj.20210101
出版者・発行元
CHEMICAL SOC JAPAN

Vibrational circular dichroism (VCD) spectra were recorded for the intercalation compounds of sodium montmorillonite co-adsorbing two kinds of metal complexes, Delta- (or Lambda-)[Ru-(phen)(3)](2+) and Lambda- (or Delta-)[Ni(phen)(3)](2+). The complexes were chosen so as to form a pseudo racemate. Notably some of the VCD signals were enhanced in comparison to the samples adsorbing each complex separately. The results were rationalized in terms of the delocalization of vibrational motions over a tightly bound molecular pair in a coherent way. The model of racemic adsorption of [M(II)(phen)(3)](2+) (M(II) = a divalent metal ion) in the interlayer space of a clay mineral was proposed.

Web of Science ® 被引用回数 : 4

リンク情報
DOI
https://doi.org/10.1246/bcsj.20210101
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000670417800009&DestApp=WOS_CPL
ID情報
  • DOI : 10.1246/bcsj.20210101
  • ISSN : 0009-2673
  • eISSN : 1348-0634
  • ORCIDのPut Code : 93545294
  • Web of Science ID : WOS:000670417800009

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