2021年6月
Stereoselective Enhancement of VCD Signals for Intercalation Compounds of Sodium Montmorillonite and Chiral Metal Complexes
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
- ,
- ,
- ,
- 巻
- 94
- 号
- 6
- 開始ページ
- 1731
- 終了ページ
- 1736
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/bcsj.20210101
- 出版者・発行元
- CHEMICAL SOC JAPAN
Vibrational circular dichroism (VCD) spectra were recorded for the intercalation compounds of sodium montmorillonite co-adsorbing two kinds of metal complexes, Delta- (or Lambda-)[Ru-(phen)(3)](2+) and Lambda- (or Delta-)[Ni(phen)(3)](2+). The complexes were chosen so as to form a pseudo racemate. Notably some of the VCD signals were enhanced in comparison to the samples adsorbing each complex separately. The results were rationalized in terms of the delocalization of vibrational motions over a tightly bound molecular pair in a coherent way. The model of racemic adsorption of [M(II)(phen)(3)](2+) (M(II) = a divalent metal ion) in the interlayer space of a clay mineral was proposed.
Web of Science ® 被引用回数 : 4
Web of Science ® の 関連論文(Related Records®)ビュー
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.20210101
- ISSN : 0009-2673
- eISSN : 1348-0634
- ORCIDのPut Code : 93545294
- Web of Science ID : WOS:000670417800009