論文

査読有り 筆頭著者
2017年4月

Metal-Free Photoinduced Decarboxylative Radical Polymerization Using Carboxylic Acids as Benign Radical Initiators: Introduction of Complex Molecules into Polymer Chain Ends

ACS MACRO LETTERS
  • Mugen Yamawaki
  • ,
  • Akari Ukai
  • ,
  • Yuki Kamiya
  • ,
  • Shinji Sugihara
  • ,
  • Miku Sakai
  • ,
  • Yasuharu Yoshimi

6
4
開始ページ
381
終了ページ
385
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1021/acsmacrolett.7b00193
出版者・発行元
AMER CHEMICAL SOC

Metal-free photoinduced decarboxylative radical polymerization of aliphatic carboxylic acids with a variety of monomers was found to proceed smoothly to give the corresponding polymers under mild conditions. Complex carboxylic acids such as those of sugars, steroids, and peptides can function as benign radical initiators via decarboxylation and can be incorporated at the polymer chain ends. This synthetic methodology represents a facile introduction of molecules and functionalities to polymers by using commercially available carboxylic acids.

リンク情報
DOI
https://doi.org/10.1021/acsmacrolett.7b00193
ID情報
  • DOI : 10.1021/acsmacrolett.7b00193

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