2000年3月
Substituent effect of 3,3,3-trifluoropropyl group on organic silanols. Palladium-mediated Mizoroki-Heck type and cross-coupling reactions
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
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- 巻
- 73
- 号
- 3
- 開始ページ
- 749
- 終了ページ
- 750
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1246/bcsj.73.749
- 出版者・発行元
- CHEMICAL SOC JAPAN
The Mizoroki-Heck type reaction of methyl(phenyl)(3,3,3-trifluoropropyl)silanol (1a) with ethyl acrylate in the presence of Pd(OAc)(2) (10 mol%) and Cu(OAc)(2)/LiOAc gave ethyl cinnamate in 70% yield. The palladium-catalyzed cross-coupling of la with 4-iodomethoxybenzene in the presence of Ag2O also afforded 4-methoxybiphenyl in 51% yield.
- リンク情報
- ID情報
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- DOI : 10.1246/bcsj.73.749
- ISSN : 0009-2673
- eISSN : 1348-0634
- Web of Science ID : WOS:000086350800030