2000年8月
Palladium-catalyzed cross-coupling of silanols, silanediols, and silanetriols promoted by silver(I) oxide
JOURNAL OF ORGANIC CHEMISTRY
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- 巻
- 65
- 号
- 17
- 開始ページ
- 5342
- 終了ページ
- 5349
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jo000679p
- 出版者・発行元
- AMER CHEMICAL SOC
Palladium-catalyzed cross-coupling of aryl- or alkenylsilanols, silanediols, and silanetriols with a variety of iodoarenes by the catalysis of palladium(0) and in the presence of silver(I) oxide furnished the coupling products in good to excellent yields. The reactions of silanediols or silanetriols under similar conditions proceeded much faster than those of silanols to afford the corresponding coupling products in excellent yields within shorter reaction periods (5-12 h). The measurement of the X-ras diffraction (XRD) pattern of the silver residue after the reaction revealed that silver(I) oxide was converted to silver(I) iodide.
- リンク情報
- ID情報
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- DOI : 10.1021/jo000679p
- ISSN : 0022-3263
- Web of Science ID : WOS:000088934300035