Papers

Jan, 2004

Synthesis and structural characterization of the first unsymmetrical diarylpalladium complex trans-Pd(C6F5)(2,4,6-C6F3H2)(PEt3)(2), derived from transmetallation between 2,4,6-trifluorophenylboronic acid and trans-Pd(C6F5)I(PEt3)(2)

CHEMICAL COMMUNICATIONS
  • Y Nishihara
    • ,
  • H Onodera
    • ,
  • K Osakada
Volume
Number
2
First page
192
Last page
193
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1039/b308741g
Publisher
ROYAL SOC CHEMISTRY
The reactions of 2,4,6-trifluorophenylboronic acid with aryl(iodo)palladium(II) complexes, trans-Pd(C6F5)I(PR3)(2)(PR3 = PEt3, PMe2Ph, PMePh2) in the presence of Ag2O afforded transPd(C6F5)(2,4,6-C6F3H2)(PR3)(2) which are stabilized by fluorine atoms in the ortho positions.
Link information
DOI
https://doi.org/10.1039/b308741g
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000188617000030&DestApp=WOS_CPL
ID information
  • DOI : 10.1039/b308741g
  • ISSN : 1359-7345
  • Web of Science ID : WOS:000188617000030
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