Papers

Peer-reviewed
2013

Synthesis of substituted [6]phenacenes through Suzuki–Miyaura coupling of polyhalobenzene with alkenylboronates and sequential intramolecular cyclization via C–H bond activation

Chem. Lett.
  • Ning-hui Chang
    • ,
  • Hiroki Mori
    • ,
  • Xi-chao Chen
    • ,
  • Yasuhiro Okuda
    • ,
  • Takeru Okamoto
    • ,
  • Yasushi Nishihara
Volume
42
Number
10
First page
1257
Last page
1259
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1246/cl.130584
Publisher
CHEMICAL SOC JAPAN
A series of substituted [6]phenacenes were synthesized through the Suzuki-Miyaura coupling and intramolecular double cyclization, using a polyhalobenzene and two different alkenylboronates. This methodology provides a direct route to unsymmetrical [6]phenacenes. The physicochemical properties of four [6]phenacenes were evaluated using UV-vis and fluorescence spectroscopies as well as cyclic voltammetry.
Link information
DOI
https://doi.org/10.1246/cl.130584
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000326313000051&DestApp=WOS_CPL
ID information
  • DOI : 10.1246/cl.130584
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000326313000051
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