Papers

Peer-reviewed
Mar, 2013

Palladium-catalyzed and copper-mediated cross-coupling reaction of aryl- or alkenylboronic acids with acid chlorides under neutral conditions: efficient synthetic methods for diaryl ketones and chalcones at room temperature

TETRAHEDRON
  • Daisuke Ogawa
  • ,
  • Keita Hyodo
  • ,
  • Masato Suetsugu
  • ,
  • Jing Li
  • ,
  • Yoshiaki Inoue
  • ,
  • Mamoru Fujisawa
  • ,
  • Masayuki Iwasaki
  • ,
  • Kentaro Takagi
  • ,
  • Yasushi Nishihara

Volume
69
Number
12
First page
2565
Last page
2571
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.tet.2013.01.058
Publisher
PERGAMON-ELSEVIER SCIENCE LTD

Palladium-catalyzed cross-coupling reaction of aryl- or alkenylboronic acids with acid chlorides in the presence of copper(I) thiophene-2-carboxylate (CuTC) as an activator in diethyl ether at room temperature under strictly non-basic conditions affords the diaryl ketones or chalcones in moderate to excellent yields. A wide range of substrates bearing an electron-donating or an electron-withdrawing substituent on the aromatic ring are compatible. (C) 2013 Elsevier Ltd. All rights reserved.

Link information
DOI
https://doi.org/10.1016/j.tet.2013.01.058
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000315610400008&DestApp=WOS_CPL
ID information
  • DOI : 10.1016/j.tet.2013.01.058
  • ISSN : 0040-4020
  • Web of Science ID : WOS:000315610400008

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