Papers

Peer-reviewed
Dec, 2011

Iron-Catalyzed Oxidation of Tertiary Amines: Synthesis of beta-1,3-Dicarbonyl Aldehydes by Three-Component C-C Couplings

ORGANIC LETTERS
  • Weiping Liu
  • ,
  • Jinhua Liu
  • ,
  • Daisuke Ogawa
  • ,
  • Yasushi Nishihara
  • ,
  • Xingwei Guo
  • ,
  • Zhiping Li

Volume
13
Number
23
First page
6272
Last page
6275
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1021/ol202749x
Publisher
AMER CHEMICAL SOC

beta-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). alpha,beta-Unsaturated aldehydes generated by tertiary amine oxidation In situ act as key intermediates under mild reaction conditions.

Link information
DOI
https://doi.org/10.1021/ol202749x
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000297274700035&DestApp=WOS_CPL
ID information
  • DOI : 10.1021/ol202749x
  • ISSN : 1523-7060
  • Web of Science ID : WOS:000297274700035

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