Dec, 2011
Iron-Catalyzed Oxidation of Tertiary Amines: Synthesis of beta-1,3-Dicarbonyl Aldehydes by Three-Component C-C Couplings
ORGANIC LETTERS
- ,
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- Volume
- 13
- Number
- 23
- First page
- 6272
- Last page
- 6275
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1021/ol202749x
- Publisher
- AMER CHEMICAL SOC
beta-1,3-Dicarbonyl aldehydes were synthesized by iron-catalyzed oxidative reactions between 1,3-dicarbonyl compounds and two molecules of tertiary amines in the presence of tert-butyl hydroperoxide (TBHP). alpha,beta-Unsaturated aldehydes generated by tertiary amine oxidation In situ act as key intermediates under mild reaction conditions.
- Link information
- ID information
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- DOI : 10.1021/ol202749x
- ISSN : 1523-7060
- Web of Science ID : WOS:000297274700035