MISC

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2018年12月1日

Chirality induction in bioorganometallic conjugates

Inorganics
  • Toshiyuki Moriuchi
  • ,
  • Satoshi D. Ohmura
  • ,
  • Takayo Moriuchi-Kawakami

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記述言語
掲載種別
書評論文,書評,文献紹介等
DOI
10.3390/inorganics6040111

© 2018 by the authors. Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates by the control of a torsional twist of the organometallic moiety. Topics covered included control of the helical chirality of 1,n'-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates, and the chirality induction of the Au(I)-Au(I) axis in the dinuclear organogold(I)-uracil conjugates.

リンク情報
DOI
https://doi.org/10.3390/inorganics6040111
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85058811855&origin=inward 本文へのリンクあり
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85058811855&origin=inward

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