2012年8月21日
Synthesis of facial cyclometalated iridium(iii) complexes triggered by tripodal ligands
Dalton Transactions
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- 巻
- 41
- 号
- 31
- 開始ページ
- 9519
- 終了ページ
- 9525
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c2dt12309f
The tripodal ligands composed of the 1,3,5-trisubstituted cyclohexyl moiety as a molecular scaffold and 2-phenylpyridyl moieties as a coordination site were designed. The homoleptic cyclometalated fac-Ir(C^N) 3 complexes could be obtained by the reaction of IrCl 3·nH 2O with the designed tripodal ligands. The single crystal X-ray structure determination confirmed the fac configuration and a distorted octahedral geometry with three intramolecular cyclometalated 2-phenylpyridyl ligands surrounding the iridium metal center. Also, the cyclohexyl scaffold was found to serve as a flexible scaffold to induce the fac configuration. The thus-obtained homoleptic cyclometalated fac-Ir(C^N) 3 complexes exhibited a broad emission band in the emission spectra at 298 K. © 2012 The Royal Society of Chemistry.
- リンク情報
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- DOI
- https://doi.org/10.1039/c2dt12309f
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000306523100031&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84864190833&origin=inward
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=84864190833&origin=inward
- ID情報
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- DOI : 10.1039/c2dt12309f
- ISSN : 1477-9226
- eISSN : 1477-9234
- SCOPUS ID : 84864190833
- Web of Science ID : WOS:000306523100031