2019年2月14日
Aerobic oxidation of alcohols using bismuth bromide as a catalyst
Tetrahedron Letters
- ,
- ,
- ,
- 巻
- 60
- 号
- 7
- 開始ページ
- 570
- 終了ページ
- 573
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.tetlet.2019.01.034
© 2019 Elsevier Ltd We developed an environmentally friendly method for aerobic oxidation of alcohols using a commercially available, relatively benign bismuth salt as a catalyst. We found that the catalytic combination of BiBr3 with nitric acid is key for enhancing the reactivity. The reaction proceeds well under air, making the use of pure oxygen unnecessary. Each of the primary or secondary alcohols tested was oxidized to the corresponding aldehydes or ketones using this protocol.
- リンク情報
- ID情報
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- DOI : 10.1016/j.tetlet.2019.01.034
- ISSN : 0040-4039
- eISSN : 1873-3581
- SCOPUS ID : 85060243566