論文

査読有り
2019年2月14日

Aerobic oxidation of alcohols using bismuth bromide as a catalyst

Tetrahedron Letters
  • Masaharu Ueno
  • ,
  • Satoshi D. Ohmura
  • ,
  • Makoto Wada
  • ,
  • Norikazu Miyoshi

60
7
開始ページ
570
終了ページ
573
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.tetlet.2019.01.034

© 2019 Elsevier Ltd We developed an environmentally friendly method for aerobic oxidation of alcohols using a commercially available, relatively benign bismuth salt as a catalyst. We found that the catalytic combination of BiBr3 with nitric acid is key for enhancing the reactivity. The reaction proceeds well under air, making the use of pure oxygen unnecessary. Each of the primary or secondary alcohols tested was oxidized to the corresponding aldehydes or ketones using this protocol.

リンク情報
DOI
https://doi.org/10.1016/j.tetlet.2019.01.034
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85060243566&origin=inward
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85060243566&origin=inward

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