2008年11月
Effects of Chemically Induced Contraction of a Coordination Polyhedron on the Dynamical Magnetism of Bis(phthalocyaninato)disprosium, a Single-4f-Ionic Single-Molecule Magnet with a Kramers Ground State
INORGANIC CHEMISTRY
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- ,
- ,
- ,
- 巻
- 47
- 号
- 22
- 開始ページ
- 10217
- 終了ページ
- 10219
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/ic8014892
- 出版者・発行元
- AMER CHEMICAL SOC
Chemically induced longitudinal contraction of the square-antiprism coordination polyhedron of a peripherically substituted bis(phthalocyaninato)dysprosiumate(III), a dysprosium-based single-4f-ionic single-molecule magnet having a J(Z) = +/- 13/2 Kramers doublet ground state, resulted in drastic changes in dynamical magnetism including a doubling of the energy barrier, a 2-order-of-magnitude decrease of the spin reversal rate, a significant rise of the blocking temperature, and the first observation of the emergence of a large remanent magnetization.
- リンク情報
- ID情報
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- DOI : 10.1021/ic8014892
- ISSN : 0020-1669
- PubMed ID : 18855382
- Web of Science ID : WOS:000260791100012