2015年4月
Reactivity of Transition-Metal Borylene Complexes: Recent Advances in B-C and B-B Bond Formation via Borylene Ligand Coupling
INORGANIC CHEMISTRY
- ,
- 巻
- 54
- 号
- 7
- 開始ページ
- 3099
- 終了ページ
- 3106
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acs.inorgchem.5b00091
- 出版者・発行元
- AMER CHEMICAL SOC
Terminal borylene complexes of group 6-10 metals have been prepared through a number of synthetic strategies, displaying a wide structural diversity with numerous coordination modes of the borylene ligand [:BR]. Earlier, amino-substituted borylenes were found to serve as borylene ligand transfer reagents to a range of organic and organometallic substrates. In contrast, aryl- and alkyl-substituted borylenes display metathesis behavior when combined with ketones. Recent studies on these complexes revealed new reactivity patterns involving borylene-borylene and carbonyl-borylene ligand coupling. Herein a brief account on the recent progress of these borylene ligand coupling reactions made in our laboratories is provided. These reactions offer unprecedented alternative methods for electron-precise B-B and B-C bond formation.
- リンク情報
- ID情報
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- DOI : 10.1021/acs.inorgchem.5b00091
- ISSN : 0020-1669
- eISSN : 1520-510X
- Web of Science ID : WOS:000352518600007