Papers

Mar, 2005

Azido(2,2 '-bipyridine)(eta(5)-pentamethylcyclopentadienyl)iridium(III) hexafluorophosphate

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE
  • T Suzuki
Volume
61
Number
First page
M488
Last page
M490
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1107/S1600536805003727
Publisher
BLACKWELL MUNKSGAARD
In the title compound, [Ir(C10H15)(N-3)(C10H8N2)]PF6, the linear azide ligand adopts an end-on terminal coordination mode with a relatively long Ir-N bond of 2.230 (6) Angstrom. The azide is asymmetric in an unusual way: the azide N-N bond adjacent to the azide Ir-N bond [1.025 (12) Angstrom] is significantly shorter than the terminal azide N-N bond [1.282 (15) Angstrom], while the azide Ir-N-N bond angle is 116.4 (6)degrees.
Link information
DOI
https://doi.org/10.1107/S1600536805003727
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000227377500040&DestApp=WOS_CPL
ID information
  • DOI : 10.1107/S1600536805003727
  • ISSN : 1600-5368
  • ORCID - Put Code : 50119495
  • Web of Science ID : WOS:000227377500040
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