2007年1月16日
Rates of Claisen rearrangement determined with a flow-type high-temperature and high-pressure NMR probe
JOURNAL OF SUPERCRITICAL FLUIDS
- ,
- ,
- ,
- 巻
- 42
- 号
- 1
- 開始ページ
- 104
- 終了ページ
- 109
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1016/j.supflu.2007.01.003
- 出版者・発行元
- ELSEVIER SCIENCE BV
Rate constants of Claisen rearrangement of allyl phenyl ether in suberitical water (272-306 degrees C) at 25.4 MPa were determined. The activation energy in this temperature range was evaluated to be 106 +/- 5 kJ mol(-1). To study the kinetics of reactions occurring in water at pressures up to 40 MPa and temperatures up to 400 degrees C, we developed a flow-through high-temperature and high-pressure NMR probe equipped with a mixing port above the RF detector. To suppress the large H-1 signal of H2O, the binomial sequence pulse technique was applied. (c) 2007 Elsevier B.V. All rights reserved.
- リンク情報
- ID情報
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- DOI : 10.1016/j.supflu.2007.01.003
- ISSN : 0896-8446
- J-Global ID : 200902240122985884
- Web of Science ID : WOS:000247337300010