論文

査読有り
2015年10月

Thermal equation of state of lawsonite up to 10 GPa and 973 K

JOURNAL OF MINERALOGICAL AND PETROLOGICAL SCIENCES
  • Nao Cai
  • ,
  • Toru Inoue
  • ,
  • Takumi Kikegawa

110
5
開始ページ
235
終了ページ
240
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.2465/jmps.150712
出版者・発行元
JAPAN ASSOC MINERALOGICAL SCIENCES

Thermal equation of state (EoS) of synthetic lawsonite [CaAl2Si2O7(OH)(2)center dot H2O] has been established using insitu X-ray diffraction methods under high pressure and high temperature. Sodium chloride NaCl was used as the pressure standard in the experiments. The unit-cell volumes were measured up to 10 GPa and 973 K after the deviatric stress was released at high temperature. The P-V-T dataset was analyzed using a Birch-Mumaghan equation of state, yielding the room pressure volume V-0 = 674.2(2) angstrom(3) and the isothermal bulk modulus at room temperature K-0 = 129(2) GPa (K' set to 4). These values are comparable with the previous studies. When fitting the high temperature data, a second order temperature derivative of the bulk modulus was considered. Unlike Daneil et al. (1999) who reported a minimum value of bulk modulus at similar to 500 K, the bulk modulus decreases with increasing temperature at least up to 973 K. The dataset yields: V-0 = 674.3(4) angstrom(3), K-0 = 128.7(15) GPa, (partial derivative K-T/partial derivative(T))(P) = -0.047(8) GPa K-1, (partial derivative(KT)-K-2/partial derivative T-2)(P) = 0.028(6) x 10(-3) GPa K-1, alpha = 3.13(25) x 10(-5) K-1, assuming K' = 4. These data can be used to calculate the density and the stability of lawsonite under high pressure and high temperature conditions.

リンク情報
DOI
https://doi.org/10.2465/jmps.150712
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000368264900004&DestApp=WOS_CPL
ID情報
  • DOI : 10.2465/jmps.150712
  • ISSN : 1345-6296
  • eISSN : 1349-3825
  • Web of Science ID : WOS:000368264900004

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