2020年5月
Highly Efficient and Selective Electrocatalytic CO2-to-CO Conversion by a Non-heme Iron Complex with an In-Plane N-4 Ligand in Heterogeneous Aqueous Media
ACS APPLIED ENERGY MATERIALS
- ,
- ,
- ,
- ,
- ,
- 巻
- 3
- 号
- 5
- 開始ページ
- 4114
- 終了ページ
- 4120
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/acsaem.9b02548
- 出版者・発行元
- AMER CHEMICAL SOC
A non-heme Fe complex with a tetradentate dicarboxamide N-4 in-plane ligand works efficiently and selectively for the electrocatalytic CO2-to-CO conversion in a homogeneous DMF solution. The complex was immobilized on a nitrogen-doped graphene (N-G) to achieve a CO2-to-CO conversion in neutral aqueous NaHCO3 solutions, affording CO with Faradaic efficiency of 90%, a current density of 6 mA cm(-2), and a turnover frequency of 2.1 s(-1), at an overpotential of 0.47 V, which is among those of the hitherto-reported efficient and selective Fe complexes electrocatalysts.
- リンク情報
- ID情報
-
- DOI : 10.1021/acsaem.9b02548
- ISSN : 2574-0962
- Web of Science ID : WOS:000537656400005