2011年9月
Planar Chirality of Twisted trans-Azobenzene Structure Induced by Chiral Transfer from Binaphthyls
JOURNAL OF ORGANIC CHEMISTRY
- ,
- ,
- ,
- 巻
- 76
- 号
- 18
- 開始ページ
- 7623
- 終了ページ
- 7628
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1021/jo201578z
- 出版者・発行元
- AMER CHEMICAL SOC
The absolute configuration of a binaphthylazobenzene dyad 2b, which has a chiral axis and a chiral plane, was determined by comparing the experimental circular dichroism (CD) spectra with the theoretical CD spectra calculated by the time-dependent (TD)-DFT method. The CD signals of the trans-azobenzene moiety indicated that the two benzene rings of this moiety are twisted unidirectionally. It is suggested that these dyads with shorter linkers may be suitable for use as chiroptical switches.
- リンク情報
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- DOI
- https://doi.org/10.1021/jo201578z
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000294702000043&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=80052750622&origin=inward
- ID情報
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- DOI : 10.1021/jo201578z
- ISSN : 0022-3263
- SCOPUS ID : 80052750622
- Web of Science ID : WOS:000294702000043