2017年4月
A copper-catalyzed Ritter-type cascade via iminoketene for the synthesis of quinazolin-4(3H)-ones and diazocines
CHEMICAL COMMUNICATIONS
- ,
- ,
- 巻
- 53
- 号
- 31
- 開始ページ
- 4362
- 終了ページ
- 4365
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1039/c7cc01406f
- 出版者・発行元
- ROYAL SOC CHEMISTRY
We have developed a copper-catalyzed Ritter-type reaction/cyclization cascade of anthranilic acids and nitriles, affording the quinazolin-4(3H)-ones. The cascade proceeds through a Ritter-type reaction capturing the iminoketene intermediates by nitriles. Furthermore, we found a novel Ritter-type reaction/condensation/intramolecular anti-Markovnikov hydroamination cascade, providing access to functionalized diazocines in one-pot.
- リンク情報
- ID情報
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- DOI : 10.1039/c7cc01406f
- ISSN : 1359-7345
- eISSN : 1364-548X
- ORCIDのPut Code : 31602069
- Web of Science ID : WOS:000399729100017