2020年2月
Tf2O-mediated Reaction of Alkenyl Sulfoxides with Unprotected Anilines in Flow Microreactors
CHEMISTRY LETTERS
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- 巻
- 49
- 号
- 2
- 開始ページ
- 160
- 終了ページ
- 163
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1246/cl.190831
- 出版者・発行元
- CHEMICAL SOC JAPAN
Flow microreactors have allowed an efficient extended Pummerer reaction of ketene dithioacetal monoxides with anilines by precise control of unstable sulfonium intermediates and spatial separation of the generation of the intermediates and the nucleophilic attack to the intermediates. A new iodonium-mediated cyclization has been devised to convert the products, thioimidates, into indoles.
- リンク情報
- ID情報
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- DOI : 10.1246/cl.190831
- ISSN : 0366-7022
- eISSN : 1348-0715
- Web of Science ID : WOS:000512886700013