論文

査読有り
2020年2月

Tf2O-mediated Reaction of Alkenyl Sulfoxides with Unprotected Anilines in Flow Microreactors

CHEMISTRY LETTERS
  • Alexandre Baralle
  • ,
  • Tomoaki Inukai
  • ,
  • Tomoyuki Yanagi
  • ,
  • Keisuke Nogi
  • ,
  • Atsuhiro Osuka
  • ,
  • Aiichiro Nagaki
  • ,
  • Jun-ichi Yoshida
  • ,
  • Hideki Yorimitsu

49
2
開始ページ
160
終了ページ
163
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1246/cl.190831
出版者・発行元
CHEMICAL SOC JAPAN

Flow microreactors have allowed an efficient extended Pummerer reaction of ketene dithioacetal monoxides with anilines by precise control of unstable sulfonium intermediates and spatial separation of the generation of the intermediates and the nucleophilic attack to the intermediates. A new iodonium-mediated cyclization has been devised to convert the products, thioimidates, into indoles.

リンク情報
DOI
https://doi.org/10.1246/cl.190831
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000512886700013&DestApp=WOS_CPL
URL
http://www.journal.csj.jp/doi/pdf/10.1246/cl.190831
ID情報
  • DOI : 10.1246/cl.190831
  • ISSN : 0366-7022
  • eISSN : 1348-0715
  • Web of Science ID : WOS:000512886700013

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