Dec, 2016
Synthesis and Characterization of an Ru-2(III, IV) Complex Containing Pyrophosphate Bridge
CHEMISTRY LETTERS
- ,
- ,
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- Volume
- 45
- Number
- 12
- First page
- 1388
- Last page
- 1390
- Language
- English
- Publishing type
- Research paper (scientific journal)
- DOI
- 10.1246/cl.160721
- Publisher
- CHEMICAL SOC JAPAN
We prepared a new Ru-2(III, IV) complex containing a pyrophosphate as the dinucleating component, by the reaction between the mononuclear complex [Ru(Me(3)tacn)Cl-3] and Na4P2O7 center dot 10H(2)O in aqueous solution. Cyclic voltammetric measurement for the complex [{Ru(Me(3)tacn)}(2)(mu-O)(mu-P2O7)]PF6 (1) in aqueous solution revealed the formation of two species with higher oxidation states, such as [O=Ru(IV)Ru(IV)=O] and [O=Ru(IV)Ru(V)=O](+). Furthermore, this complex showed activity for water oxidation reaction with Ce(NH4)(2)(NO3)(6) as the chemical oxidant in acidic aqueous solution.
- Link information
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- DOI
- https://doi.org/10.1246/cl.160721
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000389072900006&DestApp=WOS_CPL
- URL
- http://www.scopus.com/inward/record.url?eid=2-s2.0-84996606915&partnerID=MN8TOARS
- URL
- http://orcid.org/0000-0003-1022-430X
- ID information
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- DOI : 10.1246/cl.160721
- ISSN : 0366-7022
- eISSN : 1348-0715
- ORCID - Put Code : 36639592
- SCOPUS ID : 84996606915
- Web of Science ID : WOS:000389072900006