論文

査読有り
2018年12月

Model Performance Differences in Sulfate Aerosol in Winter over Japan Based on Regional Chemical Transport Models of CMAQ and CAMx

ATMOSPHERE
  • Syuichi Itahashi
  • ,
  • Kazuyo Yamaji
  • ,
  • Satoru Chatani
  • ,
  • Kunihiro Hisatsune
  • ,
  • Shinji Saito
  • ,
  • Hiroshi Hayami

9
12
開始ページ
488
終了ページ
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.3390/atmos9120488
出版者・発行元
MDPI

Sulfate aerosol (SO42-) is a major component of particulate matter in Japan. The Japanese model intercomparison study, J-STREAM, found that although SO42- is well captured by models, it is underestimated during winter. In the first phase of J-STREAM, we refined the Fe- and Mn-catalyzed oxidation and partly improved the underestimation. The winter haze in December 2016 was a target period in the second phase. The results from the Community Multiscale Air Quality (CMAQ) and Comprehensive Air quality Model with eXtentions (CAMx) regional chemical transport models were compared with observations from the network over Japan and intensive observations at Nagoya and Tokyo. Statistical analysis showed both models satisfied the suggested model performance criteria. CMAQ sensitivity simulations explained the improvements in model performance. CMAQ modeled lower SO42- concentrations than CAMx, despite increased aqueous oxidation via the metal catalysis pathway and NO2 reaction in CMAQ. Deposition explained this difference. A scatter plot demonstrated that the lower SO42- concentration in CMAQ than in CAMx arose from the lower SO2 concentration and higher SO42- wet deposition in CMAQ. The dry deposition velocity caused the difference in SO2 concentration. These results suggest the importance of deposition in improving our understanding of ambient concentration behavior.

リンク情報
DOI
https://doi.org/10.3390/atmos9120488
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000455062300032&DestApp=WOS_CPL
URL
http://www.mdpi.com/2073-4433/9/12/488
ID情報
  • DOI : 10.3390/atmos9120488
  • ISSN : 2073-4433
  • ORCIDのPut Code : 51685196
  • Web of Science ID : WOS:000455062300032

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