論文

査読有り
2016年5月

Rheology printing of an ultra-fine conductive Ru-La-O line

CERAMICS INTERNATIONAL
  • Koji Nagahara
  • ,
  • Daisuke Hirose
  • ,
  • Jinwang Li
  • ,
  • Junichi Mihara
  • ,
  • Tatsuya Shimoda

42
6
開始ページ
7730
終了ページ
7741
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1016/j.ceramint.2016.01.187
出版者・発行元
ELSEVIER SCI LTD

We previously developed a method for producing highly conductive RuO2 films using a solution-based process. In this paper, we describe the further development of this material to produce fine patterns for use in nano-sized devices through a newly developed direct imprinting process, named nano-Rheology Printing (n-RP). This process involves the fine patterning of the precursor gel by an imprinting process to generate fine solid patterns while avoiding potential pattern breakage during sintering. The pattern breaking is typically caused by the crystallization nature of an oxide material, which may become more prominent when the size is reduced to less than 100 nm. To solve this problem, we investigated the properties of the Ru-La system and observed that a small addition of La to Ru greatly improved the viscoelastic property of the gel without any noticeable reduction of conductivity. The Ru La system also exhibited an amorphous state over a wide composition range, and thus the fine gel patterns produced by the imprinting process were resistant to breakage during sintering. These unique properties of the Ru La system were thought to result from the molecular crystalline nature of the La gel. Based on the results, the n-RP method could successfully fabricate a fine line of the Ru-0.75-La0.25O oxide with a width of 30 nm and with good conductivity. (C) 2016 Elsevier Ltd and Techna Group S.r.l. All rights reserved.

リンク情報
DOI
https://doi.org/10.1016/j.ceramint.2016.01.187
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000372676000143&DestApp=WOS_CPL
ID情報
  • DOI : 10.1016/j.ceramint.2016.01.187
  • ISSN : 0272-8842
  • eISSN : 1873-3956
  • Web of Science ID : WOS:000372676000143

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