論文

査読有り
2019年4月12日

Electron diffraction study of crystal structures of (Sr1−xBax)2Nb2O7

Physical Review Materials
  • Bikas Aryal
  • ,
  • Daisuke Morikawa
  • ,
  • Kenji Tsuda
  • ,
  • Shinya Tsukada
  • ,
  • Yukikuni Akishige
  • ,
  • Masami Terauchi

3
4
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1103/physrevmaterials.3.044405
出版者・発行元
American Physical Society (APS)

Selected-area electron diffraction and convergent-beam electron diffraction (CBED) techniques are used to reveal the Ba doping effect on the crystal structure of (Sr1-xBax)(2)Nb2O7 [SBN(x)] in the temperature range from 293 to 693 K. Ba doping of Sr2Nb2O7 (SN) causes weakening of the incommensurate modulation and deviation from the C-centered lattice. On the other hand, symmetries of fundamental reflections in CBED patterns of SBN(x) are seen to be the same as those of SN, showing a small structural deviation from Cmc2(1). Crystal symmetries above and below the temperature of a relaxorlike dielectric anomaly in SBN (x = 0.32) at 465 K remain unchanged. CBED experiments with a nanometer-sized electron probe do not show any indication of the presence of a nanodomain around this temperature. However, the presence of a few-micron-sized polar-inversion domains is found at around 573 K in SBN (x = 0.32). The origin of the reported relaxorlike dielectric anomaly in SBN (x = 0.32) is discussed on the basis of the experimental results of CBED.

リンク情報
DOI
https://doi.org/10.1103/physrevmaterials.3.044405
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000464762100001&DestApp=WOS_CPL
URL
https://link.aps.org/article/10.1103/PhysRevMaterials.3.044405
URL
http://harvest.aps.org/v2/journals/articles/10.1103/PhysRevMaterials.3.044405/fulltext
ID情報
  • DOI : 10.1103/physrevmaterials.3.044405
  • ISSN : 2475-9953
  • eISSN : 2475-9953
  • ORCIDのPut Code : 56437760
  • Web of Science ID : WOS:000464762100001

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