Daisuke Hirose

Profile Information

Affiliation: Institute of Science and Engineering Faculty of Chemistry, Kanazawa University

Degree: 博士（理学）(金沢大学)

J-GLOBAL ID: 201801013222946479
researchmap Member ID: B000290435

External link: http://kohka.ch.t.kanazawa-u.ac.jp/lab5/saito/index.html

Research Interests

Research Areas

Nanotechnology/Materials / Synthetic organic chemistry /

Research History

Nov, 2019 - Present

Institute of Science and Engineering, Faculty of Chemistry, Kanazawa University
Jan, 2019 - Oct, 2019

Institute for Frontier Science Initiative, Kanazawa University
Aug, 2017 - Dec, 2018

金沢大学
Apr, 2017 - Jul, 2017

金沢大学
Apr, 2016 - Mar, 2017

日本学術振興会特別研究員（PD）
Apr, 2014 - Mar, 2016

日本学術振興会特別研究員（DC1）

Education

Oct, 2013 - Mar, 2016

Graduate School of Natural Science and Technology, Kanazawa University
Apr, 2013 - Sep, 2013

Graduate School of Natural Science and Technology, Kanazawa University
Apr, 2011 - Mar, 2013

Kanazawa University
Apr, 2007 - Mar, 2011

Department of Pharmaceutical Sciences, Faculty of Pharmaceutical Sciences, Kanazawa University

Awards

Mar, 2024

日本化学会若い世代の特別講演証, 日本化学会

廣瀬大祐
Aug, 2021

パブリシティ賞, 高分子学会

惣名翔大, 廣瀬大祐, 谷口剛史, 西村達也, 前田勝浩
Nov, 2019

第５回若手研究者奨励賞, 金沢大学・イノベーション推進機構協力会

廣瀬大祐
Jun, 2018

第７回新化学技術研究奨励賞, 公益社団法人新化学技術推進協会

廣瀬大祐

Papers

Dehydrogenative silylation of cellulose in ionic liquid

Daisuke Hirose, Samuel Budi Wardhana Kusuma, Akina Yoshizawa, Naoki Wada, Kenji Takahashi

Green Chemistry, 25(18) 7062-7067, Aug 18, 2023 Peer-reviewedLead authorCorresponding author
Helicity induction and memory of a lipophilic Brønsted acid-type poly(phenylacetylene) in non-polar solvents

Yuki Nishikawa, Daisuke Hirose, Shota Sona, Katsuhiro Maeda

Chemical Communications, 59(53) 8226-8229, May 19, 2023 Peer-reviewedLead authorCorresponding author
Ultra-fast One-Handed Helix Induction and Its Static Helicity Memory in a Poly(biphenylylacetylene) with a Catalytic Amount of Chiral Ammonium Salts

Mayu Fukuda, Mai Morikawa, Daisuke Hirose, Tsuyoshi Taniguchi, Tatsuya Nishimura, Eiji Yashima, Katsuhiro Maeda

Angewandte Chemie - International Edition, 62(15) e202217020, Apr, 2023 Peer-reviewed
Continuous process of cellulose dissolution and transesterification reaction catalysed by ionic liquid in twin screw extruder

Romain Milotskyi, Gyanendra Sharma, Tetsuo Fujie, Daisuke Hirose, Naoki Wada, Kenji Takahashi

Reaction Chemistry and Engineering, 8(6) 1395-1402, Mar 23, 2023 Peer-reviewed
Synthesis of an Immobilized Three-state Switchable Chiral Stationary Phase for HPLC Using a Metal Cation-responsive Optically Active Poly(phenylacetylene) Derivative and Its Chiral Recognition Ability

Mayu Fukuda, Tatsuya Nishimura, Daisuke Hirose, Katsuhiro Maeda

Chemistry Letters, 52(3) 136-139, Mar 5, 2023 Peer-reviewed
Aryloxy Ionic Liquid-Catalyzed Homogenous Esterification of Cellulose with Low-Reactive Acyl Donors

Akina Yoshizawa, Chie Maruyama, Samuel Budi Wardhana Kusuma, Naoki Wada, Kosuke Kuroda, Daisuke Hirose, Kenji Takahashi

Polymers, 15(2), Jan 13, 2023 Peer-reviewedCorresponding author
Thermally stable and rewritable circularly polarized luminescent helical poly(diphenylacetylene)s: stabilization of macromolecular helicity memory via reversible ion-pair formation

Shota Sona, Daisuke Hirose, Yuki Kurihara, Katsuhiro Maeda

Journal of Materials Chemistry C, 11(4) 1271-1277, Dec 21, 2022 Lead author
Enantioseparation on helical poly(diphenylacetylene)s bearing optically-active pendants: Effects of differences in higher-order structures of kinetically-trapped and thermodynamically-stable states on chiral recognition ability

Daisuke Hirose, Koji Ogino, Kosei Uematsu, Katsuhiro Maeda

Journal of Chromatography A, 1675, Jul 19, 2022 Lead author
Characterization and application of carboxylate-type zwitterions synthesized by one-step

Tetsuo Komori, Yui Kato, Kojiro Ishibashi, Kazuaki Ninomiya, Naoki Wada, Daisuke Hirose, Kenji Takahashi, Eishu Hirata, Kosuke Kuroda

Journal of Ionic Liquids, 2(1) 100027-100027, Jun, 2022
Solvent-dependent helix inversion in optically active poly(diphenylacetylene)s and their chiral recognition abilities as chiral stationary phases for high-performance liquid chromatography

Daisuke Hirose, Mai Nozaki, Miyuki Maruta, Katsuhiro Maeda

Chirality, 2022 Lead author
Visualisation of helical structures of poly(diphenylacetylene)s bearing chiral amide pendants by atomic force microscopy

Ayhan Yurtsever, Sandip Das, Tatsuya Nishimura, Rafael Rodríguez, Daisuke Hirose, Kazuki Miyata, Ayumi Sumino, Takeshi Fukuma, Katsuhiro Maeda

Chemical Communications, 57(92) 12266-12269, Nov 28, 2021 Peer-reviewed
Direct Synthesis of Full-Biobased Cellulose Esters from Essential Oil Component alpha,beta-Unsaturated Aldehydes

Samuel Budi Wardhana Kusuma, Daisuke Hirose, Akina Yoshizawa, Laszlo Szabo, Daiki Ina, Naoki Wada, Kenji Takahashi

ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 9(25) 8450-8457, Jun, 2021 Peer-reviewedCorresponding author
Helical springs as a color indicator for determining chirality and enantiomeric excess

Katsuhiro Maeda, Daisuke Hirose, Mai Nozaki, Yoichi Shimizu, Taro Mori, Kentaro Yamanaka, Koji Ogino, Tatsuya Nishimura, Tsuyoshi Taniguchi, Munetsugu Moro …

SCIENCE ADVANCES, 7(27), Jun, 2021 Peer-reviewed
Mussel-inspired design of a carbon fiber−cellulosic polymer interface toward engineered biobased carbon fiber-reinforced composites

Laszlo Szabo, Sari Imanishi, Daisuke Hirose, Takayuki Tsukegi, Naoki Wada, Kenji Takahashi

ACS Omega, 5(42) 27072-27082, Oct 27, 2020
Understanding and suppression of side reaction during transesterification of phenolic hydroxyl groups of lignin with vinyl ester

Shiori Suzuki, Akinari Ishikuro, Yosuke Hamano, Daisuke Hirose, Naoki Wada, Kenji Takahashi

Chemistry Letters, 49(8) 900-904, Aug 5, 2020
Synthesis of a poly(diphenylacetylene) bearing optically active anilide pendants and its application to a chiral stationary phase for high-performance liquid chromatography

Mai Nozaki, Daisuke Hirose, Katsuhiro Maeda

Journal of Chromatography A, 1622, Jul 5, 2020 Peer-reviewedLead author
Helix-Sense-Selective Synthesis of Right- and Left-Handed Helical Luminescent Poly(diphenylacetylene)s with Memory of the Macromolecular Helicity and Their Helical Structures.

Katsuhiro Maeda, Mai Nozaki, Kengo Hashimoto, Kouhei Shimomura, Daisuke Hirose, Tatsuya Nishimura, Go Watanabe, Eiji Yashima

Journal of the American Chemical Society, 142(16) 7668-7682, Apr 22, 2020 Peer-reviewed
Direct one-step synthesis of a formally fully bio-based polymer from cellulose and cinnamon flavor

Hirose Daisuke, Kusuma Samuel, Budi Wardhana, Ina Daiki, Wada Naoki, Takahashi Kenji

GREEN CHEMISTRY, 21(18) 4927-4931, Sep 21, 2019 Peer-reviewedLead authorCorresponding author
Transesterification Reaction of Cellulose with Inactive Esters in Ionic Liquids Acting as Both Catalysts and Solvents

Kusuma Samuel B. W, Hirose Daisuke, Takahashi Kenji

CHEMISTRY LETTERS, 48(9) 1122-1125, Sep, 2019 Peer-reviewedCorresponding author
Macromolecular helicity control of poly(phenyl isocyanate)s with a single stimuli-responsive chiral switch

Fukuda Mayu, Rodriguez Rafael, Fernandez Zulema, Nishimura Tatsuya, Hirose Daisuke, Watanabe Go, Quinoa Emilio, Freire Felix, Maeda Katsuhiro

CHEMICAL COMMUNICATIONS, 55(55) 7906-7909, Jul 14, 2019 Peer-reviewed

Books and Other Publications

Biomass Conversion Process Innovated by Ionic Liquid

Daisuke Hirose, Naoki Wada, Kenji Takahashi

Jun, 2020
人工分子マシンで機能性分子を精密に作る―リボソーム模倣型分子マシン―

廣瀬大祐, 前田勝浩

化学同人、月刊『化学』、「最新のトピックス」 2019年3月号, Feb, 2019
セルロースベース炭素繊維強化プラスチック(CFRP)の機能向上

和田直樹, ászló Szabó, 廣瀬大祐, 高橋憲司

月刊プラスチックスエージ 2019年3月号, Feb, 2019

Presentations

Development of Helical Polymer-based Chiral Materials Focused on Non-privileged Host Structure

Daisuke Hirose

Mar 18, 2024 Invited
キラル炭化水素すら識別可能なキラル指示薬

廣瀬大祐

金沢大学新技術説明会, Aug 17, 2023 Invited
ラセン状ナノカーボン材料を用いた吸着特性の制御が可能な分離吸着材料の開発

廣瀬大祐

公益社団法人新化学技術推進協会エネルギー・資源技術部会資源代替材料分科会・勉強会, Jun 7, 2023 Invited
次世代の高分子合成と機能開拓

廣瀬大祐

金沢大学産学連携協力会第21回金沢大学研究会見学会, Mar 15, 2023 Invited
Ionic Liquid Catalyst for Polysaccharide Modification

Daisuke Hirose

7th International Conference on CATALYSIS AND CHEMICAL ENGINEERING (CCE-2023), Feb 24, 2023 Invited
Direct Synthesis of Fully Bio-based Polymer from Cellulose and Natural Aldehyde

Daisuke Hirose

ICMSE 2022, Oct 5, 2022 Invited
プラスワンで映える多機能性分子材料系の開発

廣瀬大祐

2022年第6回藤内研究室講演会, Jul 2, 2022 Invited
Direct One-step Synthesis of Fully Bio-based Polymer from Polysaccharide and Natural Aldehyde in Ionic Liquid

Daisuke Hirose

SEMINAR NASIONAL KIMIA DAN PENDIDIKAN KIMIA 2021, Oct 9, 2021 Invited
環境調和型プロセスを指向した縮合反応の開発と応用

廣瀬大祐

群馬先端材料シンポジウム2019, Mar 19, 2019 Invited
イオン液体の触媒機能を用いたセルロースのエステル交換反応

廣瀬大祐, 野村周平, 丸山千恵, Kusuma Samuel, 高橋憲司

第67回高分子討論会 (S17 近未来の環境を考える高分子素材; 6)グリーンケミストリーに対応した高分子材料), Sep 12, 2018 Invited
Helicity Induction and Memory in a Poly(biphenylylacetylene) with Chiral Ammonium Salts and Its Chiral Amplification Behavior

Daisuke Hirose, Mai Morikawa, Tomoyuki Ikai, Shigeyoshi Kanoh, Katsuhiro Maeda, Eiji Yashima

Molecular Chirality Asia 2018, Jul, 2018
Esterification of Cellulose with Methyl Ester in Imidazolium-based Ionic Liquid

Samuel Kusuma, Shuhei Nomura, Makoto Yamaguchi, Daisuke Hirose, Yoshiro Yasaka, Kazuaki Ninomiya, Kenji Takahashi

255th ACS National Meeting & Exposition, Mar, 2018
Synthesis of Rh Complexes Bearing Poly(diphenylacetylene)s with Macromolecular Helicity Memory as Chiral Ligands and Their Use as Asymmetric Catalysts

Daisuke Hirose, Haruka Matsukawa, Tatsuya Nishimura, Shigeyoshi Kanoh, Katsuhiro Maeda

Molecular Chirality 2017; ISCD-29, Jul, 2017

Professional Memberships

Research Projects

らせん高分子を用いた万能キラル可視化技術の開発と未可視キラリティへの挑戦

科学研究費助成事業若手研究, 若手研究, 日本学術振興会, Apr, 2023 - Mar, 2026

廣瀬大祐
環境影響をポジティブに変える循環型オールバイオマス樹脂の高速製造技術の開発

科学研究費助成事業基盤研究(B), 基盤研究(B), 日本学術振興会, Apr, 2022 - Mar, 2026

高橋憲司, 和田直樹, 廣瀬大祐
Development of Precision Synthetic Method and Functions of Helical Nanocarbon Poly(diphenylacetylene)s

Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (A), Grant-in-Aid for Scientific Research (A), Japan Society for the Promotion of Science, Apr, 2021 - Mar, 2025
Development of Functional Materials Exhibiting Mobility Based on Expansion and Contraction of Helical Polymer Chains

Grants-in-Aid for Scientific Research Grant-in-Aid for Challenging Research (Exploratory), Grant-in-Aid for Challenging Research (Exploratory), Japan Society for the Promotion of Science, Jul, 2021 - Mar, 2024
Continuous direct biomass conversion process using ionic liquids

Grants-in-Aid for Scientific Research, Grant-in-Aid for Scientific Research (B), Japan Society for the Promotion of Science, Apr, 2018 - Mar, 2022

Takahashi Kenji
ラセン高分子の記憶操作技術に基づく高感度キラルセンシング

科学研究費補助金若手研究, 日本学術振興会, Apr, 2019 - Mar, 2021

廣瀬大祐
大型３DプリンティングによるCFRPペレットを用いた革新的建築壁モジュールの設計方法に関する研究

COI若手連携研究ファンド, 国立研究開発法人科学技術振興機構, Apr, 2018 - Mar, 2019

廣瀬大祐
工業的利用を見据えた触媒的光延反応の開発研究

科学研究費補助金特別研究員奨励費, 日本学術振興会, Apr, 2014 - Mar, 2017

廣瀬大祐

Industrial Property Rights

特許第7265754号多糖類誘導体の製造方法、及びリグニン誘導体の製造方法

廣瀬大祐, Samuel Budi Wardhana Kusuma, 伊奈大希, 和田直樹, 高橋憲司
特願2023-061699 キラルセンサー

廣瀨大祐, 惣名翔大, 松永匡生, 前田勝浩
特許第7223406号多糖類誘導体の製造方法、及びリグニン誘導体の製造方法

廣瀬大祐, Samuel Budi Wardhana Kusuma, 丸山千恵, 和田直樹, 高橋憲司
特許第7038994号炭素繊維強化プラスチックの製造法、炭素繊維強化プラスチック及びセルロース系樹脂

覚知亮平, 廣瀬大祐, 仁宮一章, ラスロザボ, 高橋憲司
特許第6934183号比色蛍光検出型アニオンセンサー

前田勝浩, 廣瀬大祐, 清水耀一
特許第6874990号比色検出型キラルセンサーを用いる光学活性キラルアミン化合物のキラリティー及び光学純度の決定法

前田勝浩, 廣瀬大祐, 森太郎
特願PCT/JP2019/50555 多糖類のシリルエーテル化物の製造方法

廣瀬大祐, Samuel Budi Wardhana Kusuma, 和田直樹, 高橋憲司, 松村裕之
特願PCT_JP2019/22237 多糖類誘導体の製造方法

廣瀬大祐, 玄田雅志, 和田直樹, 瀧健太郎, 高橋憲司, 松村裕之
特願2017-077068 キラルアミンセンサー

前田勝浩, 廣瀬大祐, 水上あずさ
特開2014-148477 反応方法及びそれに用いる新規アゾ化合物

谷口剛史, 廣瀬大祐, 石橋弘行

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Books and Other Publications

Presentations

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