論文

査読有り
2017年1月

Nickel-Catalyzed CO2 Rearrangement of Enol Metal Carbonates for the Efficient Synthesis of β-Ketocarboxylic Acids

Angewandte Chemie - International Edition
  • Ryo Ninokata
  • ,
  • Tatsuya Yamahira
  • ,
  • Gen Onodera
  • ,
  • Masanari Kimura

56
1
開始ページ
208
終了ページ
211
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/anie.201609338

© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 4-Methylene-1,3-dioxolan-2-ones underwent oxidative addition of a Ni0catalyst in the presence of Me2Al(OMe), followed by a coupling reaction with alkynes, to form δ,ϵ-unsaturated β-ketocarboxylic acids with high regio- and stereoselectivity. The reaction proceeds by [1,3] rearrangement of an enol metal carbonate intermediate and the formal reinsertion of CO2.

リンク情報
DOI
https://doi.org/10.1002/anie.201609338
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000394861200026&DestApp=WOS_CPL
URL
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85006756969&origin=inward
ID情報
  • DOI : 10.1002/anie.201609338
  • ISSN : 1433-7851
  • eISSN : 1521-3773
  • SCOPUS ID : 85006756969
  • Web of Science ID : WOS:000394861200026

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