2017年1月
Nickel-Catalyzed CO2 Rearrangement of Enol Metal Carbonates for the Efficient Synthesis of β-Ketocarboxylic Acids
Angewandte Chemie - International Edition
- ,
- ,
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- 巻
- 56
- 号
- 1
- 開始ページ
- 208
- 終了ページ
- 211
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/anie.201609338
© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim 4-Methylene-1,3-dioxolan-2-ones underwent oxidative addition of a Ni0catalyst in the presence of Me2Al(OMe), followed by a coupling reaction with alkynes, to form δ,ϵ-unsaturated β-ketocarboxylic acids with high regio- and stereoselectivity. The reaction proceeds by [1,3] rearrangement of an enol metal carbonate intermediate and the formal reinsertion of CO2.
- リンク情報
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- DOI
- https://doi.org/10.1002/anie.201609338
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000394861200026&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85006756969&origin=inward
- ID情報
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- DOI : 10.1002/anie.201609338
- ISSN : 1433-7851
- eISSN : 1521-3773
- SCOPUS ID : 85006756969
- Web of Science ID : WOS:000394861200026