論文

査読有り 筆頭著者
2023年1月6日

Oxygen potential, oxygen diffusion, and defect equilibria in UO2±x

Frontiers in Nuclear Engineering
  • Masashi Watanabe
  • ,
  • Masato Kato

1
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.3389/fnuen.2022.1082324
出版者・発行元
Frontiers Media {SA}

Since the oxygen potential and the oxygen diffusion coefficient of UO2 have a significant impact on fuel performance, many experimental data have been obtained. However, experimental data of the oxygen potential and the oxygen diffusion coefficient in the high temperature region above 1673 K are very limited. In the present study, we aimed to obtain these data and analyze them by defect chemistry. the oxygen potentials and the oxygen chemical diffusion coefficient of UO2 were measured by the gas equilibrium method in the near stoichiometric region at temperatures ranging from 1673 to 1873 K. A data set of oxygen potentials was made together with literature data and analyzed by defect chemistry. The oxygen potential of UO2 was determined as a function of O/U ratio and temperature, and an equation representing the relationship was derived. The oxygen chemical diffusion coefficient values obtained in this study were reasonably close to the literature values. The oxygen partial pressure dependence of the oxygen chemical diffusion coefficients was predicted from the evaluated results of the oxygen potential data, but no clear dependence was observed.

リンク情報
DOI
https://doi.org/10.3389/fnuen.2022.1082324
URL
https://www.frontiersin.org/articles/10.3389/fnuen.2022.1082324/full
ID情報
  • DOI : 10.3389/fnuen.2022.1082324
  • ISSN : 2813-3412
  • eISSN : 2813-3412
  • ORCIDのPut Code : 128779725

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