MISC

査読有り 招待有り 筆頭著者 責任著者 本文へのリンクあり 国際誌
2020年6月4日

Catalytic conversion of ethane to valuable products through non-oxidative dehydrogenation and dehydroaromatization

RSC Advances
  • Hikaru Saito
  • ,
  • Yasushi Sekine

10
36
開始ページ
21427
終了ページ
21453
記述言語
英語
掲載種別
記事・総説・解説・論説等(学術雑誌)
DOI
10.1039/d0ra03365k

Chemical utilization of ethane to produce valuable chemicals has become especially attractive since the expanded utilization of shale gas in the United States and associated petroleum gas in the Middle East. Catalytic conversion to ethylene and aromatic hydrocarbons through non-oxidative dehydrogenation and dehydroaromatization of ethane (EDH and EDA) are potentially beneficial technologies because of their high selectivity to products. The former represents an attractive alternative to conventional thermal cracking of ethane. The latter can produce valuable aromatic hydrocarbons from a cheap feedstock. Nevertheless, further progress in catalytic science and technology is indispensable to implement these processes beneficially. This review summarizes progress that has been achieved with non-oxidative EDH and EDA in terms of the nature of active sites and reaction mechanisms. Briefly, platinum-, chromium- and gallium-based catalysts have been introduced mainly for EDH, including effects of carbon dioxide co-feeding. Efforts to use EDA have emphasized zinc-modified MFI zeolite catalysts. Finally, some avenues for development of catalytic science and technology for ethane conversion are summarized.

リンク情報
DOI
https://doi.org/10.1039/d0ra03365k 本文へのリンクあり
共同研究・競争的資金等の研究課題
金属担持触媒によるエタンからエチレン及び芳香族化合物への転換
Scopus
https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85086517428&origin=inward 本文へのリンクあり
Scopus Citedby
https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85086517428&origin=inward
ID情報
  • DOI : 10.1039/d0ra03365k
  • eISSN : 2046-2069
  • SCOPUS ID : 85086517428
  • 共同研究・競争的資金等の研究課題の業績ID : 32559055

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