2010年3月
ギブスの熱力学と統計力学 : 物理化学の視点から
科学史研究. 第II期
- 巻
- 49
- 号
- 253
- 開始ページ
- 1
- 終了ページ
- 10
- 記述言語
- 日本語
- 掲載種別
- 研究論文(学術雑誌)
- 出版者・発行元
- 日本科学史学会
This paper reveals that Josiah Willard Gibbs (1839-1903) attempted to explain certain chemical properties of matter, such as osmotic pressure of "diaphragms" (semi-permeable membranes) and electromotive force of chemical cells, from his theory of statistical mechanics, i.e., Elementary Principles in Statistical Mechanics (1902; EPSM). To begin with, I examine his thermodynamical theory developed in "On the Equilibrium of Heterogeneous Substances" (1876/78; EHS). Later, I attempt to support the above claim by analyzing his theory of statistical mechanics. In EHS and his later discussions on ...
- リンク情報
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- CiNii Articles
- http://ci.nii.ac.jp/naid/110007621742
- ID情報
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- ISSN : 0022-7692
- CiNii Articles ID : 110007621742