論文

査読有り
2012年2月

The rates of sea salt sulfatization in the atmosphere and surface snow of inland Antarctica

JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES
  • Yoshinori Iizuka
  • ,
  • Akira Tsuchimoto
  • ,
  • Yu Hoshina
  • ,
  • Toshimitsu Sakurai
  • ,
  • Margareta Hansson
  • ,
  • Torbjorn Karlin
  • ,
  • Koji Fujita
  • ,
  • Fumio Nakazawa
  • ,
  • Hideaki Motoyama
  • ,
  • Shuji Fujita

117
開始ページ
D04308
終了ページ
10
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1029/2011JD016378
出版者・発行元
AMER GEOPHYSICAL UNION

Most of the aerosol particles present in the surface snow and ice of inland Antarctica come from primary sea salt (sodium chloride) and marine biological activity (methansulfonic and sulfuric acids). Melted water from surface snow, firn, and Holocene ice contains mainly sodium, chloride, and sulfate ions. Although it is well known that sea salt aerosols react rapidly with sulfuric acid, a process known as sulfatization, it is not known when this process takes place. In this research we undertake to measure the proportion of sea salt aerosols that undergo sulfatization in the atmosphere and surface snow, as opposed to deeper ice, in order to understand the suitability of sea salt aerosols as a proxy for past climates in deep ice cores. We directly measure the sulfatization rates in recently fallen snow (0-4 m in depth) collected at the Dome Fuji station, using X-ray dispersion spectroscopy to determine the constituent elements of soluble particles and computing the molar ratios of sodium chloride and sodium sulfate. We estimate that about 90% of the initial sea salt aerosols sulfatize as they are taken up by precipitation over Dome Fuji or in the snowpack within one year after being deposited on the ice sheet.

リンク情報
DOI
https://doi.org/10.1029/2011JD016378
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000301129700001&DestApp=WOS_CPL
URL
http://onlinelibrary.wiley.com/doi/10.1029/2011JD016378/full
ID情報
  • DOI : 10.1029/2011JD016378
  • ISSN : 2169-897X
  • eISSN : 2169-8996
  • Web of Science ID : WOS:000301129700001

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