Papers

Jul, 2007

Magnetic and dielectric properties of RFe2O4, RFeMO4, and RGaCuO4 (R=Yb and Lu, M=Co and Cu)

PHYSICAL REVIEW B
  • Kenji Yoshii
  • ,
  • Naoshi Ikeda
  • ,
  • Yoji Matsuo
  • ,
  • Yoichi Horibe
  • ,
  • Shigeo Mori

Volume
76
Number
2
First page
1
Last page
12
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1103/PhysRevB.76.024423
Publisher
AMER PHYSICAL SOC

The magnetic and dielectric properties have been investigated for the isostructural oxides of RFe2O4, RFeMO4, and RGaCuO4 (R=Yb and Lu, M=Co and Cu). The magnetization measurements for RFe2O4 showed ferrimagnetic ordering at similar to 250 K. This system also exhibited large dielectric constants of similar to 10 000-30 000 at around room temperature, which is attributable to the charge-ordering-induced ferroelectricity, as was proposed in our recent paper. The magnetic transition temperatures are lowered to similar to 45-90 K for RFeMO4. Magnetic ordering is not found for RGaCuO4. ac magnetic susceptibility measurements indicate that magnetic ordering becomes short-ranged by the substitution at the Fe site. The overall characteristic behavior of the magnetic properties is explained in terms of the change of a spin value as well as the dilution of magnetic interactions. Although the ac dielectric measurements show the existence of polar regions in each material, the dielectric constants below 300 K become smaller in the order of RFe2O4, RFeCoO4, RFeCuO4, and RGaCuO4. From the analysis of the dielectric dispersion, the distribution of the fluctuation time of polar regions is wider in RFeCoO4, RFeCuO4, and RGaCuO4 than in RFe2O4; a coherent motion of polar regions is suppressed in the substituted systems. By comparison to the results from the magnetic measurements, the dielectric properties are discussed in connection with a charge transfer between the transition-metal 3d orbitals, consistently with the proposed mechanism of the ferroelectricity in RFe2O4.

Link information
DOI
https://doi.org/10.1103/PhysRevB.76.024423
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000248496200077&DestApp=WOS_CPL
ID information
  • DOI : 10.1103/PhysRevB.76.024423
  • ISSN : 1098-0121
  • eISSN : 2469-9969
  • Web of Science ID : WOS:000248496200077

Export
BibTeX RIS