2018年12月
Synthesis of P-stereogenic phosphonothioates via alcoholysis of phosphonothioates with a binaphthyl group
Heteroatom Chemistry
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- 巻
- 29
- 号
- 5-6
- 記述言語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/hc.21448
© 2018 Wiley Periodicals, Inc. The reaction of phosphonothioates having a binaphthyl group with alkoxides proceeded via transfer of the axial chirality of the binaphthyl group to the central chirality of the phosphorus atom to give P-stereogenic phosphonothioates with moderate-to-excellent diastereoselectivities. The reaction of phosphonoselenoates also proceeded in a similar fashion. The selenium atom of the obtained product could be excluded with tributylphosphine to give a trivalent phosphonite, which was isolated as a boron complex.
- リンク情報
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- DOI
- https://doi.org/10.1002/hc.21448
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000457016400016&DestApp=WOS_CPL
- Scopus
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85056635542&origin=inward 本文へのリンクあり
- Scopus Citedby
- https://www.scopus.com/inward/citedby.uri?partnerID=HzOxMe3b&scp=85056635542&origin=inward
- ID情報
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- DOI : 10.1002/hc.21448
- ISSN : 1042-7163
- eISSN : 1098-1071
- SCOPUS ID : 85056635542
- Web of Science ID : WOS:000457016400016