論文

査読有り 本文へのリンクあり
2018年12月

Synthesis of P-stereogenic phosphonothioates via alcoholysis of phosphonothioates with a binaphthyl group

Heteroatom Chemistry
  • Kazuma Kuwabara
  • ,
  • Yuuki Maekawa
  • ,
  • Masahiro Ebihara
  • ,
  • Toshifumi Maruyama
  • ,
  • Toshiaki Murai

29
5-6
記述言語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/hc.21448

© 2018 Wiley Periodicals, Inc. The reaction of phosphonothioates having a binaphthyl group with alkoxides proceeded via transfer of the axial chirality of the binaphthyl group to the central chirality of the phosphorus atom to give P-stereogenic phosphonothioates with moderate-to-excellent diastereoselectivities. The reaction of phosphonoselenoates also proceeded in a similar fashion. The selenium atom of the obtained product could be excluded with tributylphosphine to give a trivalent phosphonite, which was isolated as a boron complex.

リンク情報
DOI
https://doi.org/10.1002/hc.21448
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000457016400016&DestApp=WOS_CPL
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https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85056635542&origin=inward 本文へのリンクあり
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ID情報
  • DOI : 10.1002/hc.21448
  • ISSN : 1042-7163
  • eISSN : 1098-1071
  • SCOPUS ID : 85056635542
  • Web of Science ID : WOS:000457016400016

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