2014年10月
Anionic and cationic nanocomposite hydrogels reinforced with cellulose and chitin nanowhiskers: effect of electrolyte concentration on mechanical properties and swelling behaviors
POLYMERS FOR ADVANCED TECHNOLOGIES
- ,
- 巻
- 25
- 号
- 10
- 開始ページ
- 1108
- 終了ページ
- 1115
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/pat.3361
- 出版者・発行元
- WILEY
Various nanocomposite gels were prepared using cellulose nanowhiskers (CNWs) or chitin nanowhiskers (ChNWs) as reinforcing fillers and hydroxypropyl cellulose (HPC), carboxymethyl cellulose (CMC), or chitosan as network polymers. The use of CNWs with low surface charge induced significant CNWs aggregations, which were well explained by depletion effect. Young's modulus E and swelling ratio Q of CNWs/HPC center dot CMC gels were highest at zero electrolyte concentration and decreased above 0.01M electrolyte, whereas stress at break sigma of the gels showed its minimum at zero electrolytes and increased with an addition of electrolytes. In the case of ChNWs/chitosan gels, maximum of E and Q was located at 0.01M electrolyte concentration, and sigma did not indicate clear tendency with electrolyte concentration. Although all gels indicated an increase in E and a decrease in Q with an increase in whisker content, the most remarkable changes were observed under an absence of electrolytes, whereas the changes under the presence of electrolytes were somewhat negligible. Copyright (c) 2014 John Wiley & Sons, Ltd.
- リンク情報
- ID情報
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- DOI : 10.1002/pat.3361
- ISSN : 1042-7147
- eISSN : 1099-1581
- Web of Science ID : WOS:000342632900003