Papers

Peer-reviewed International journal
Mar, 2016

Advanced instrumentation for DNP-enhanced MAS NMR for higher magnetic fields and lower temperatures.

Journal of magnetic resonance (San Diego, Calif. : 1997)
  • Yoh Matsuki
  • ,
  • Toshitaka Idehara
  • ,
  • Jun Fukazawa
  • ,
  • Toshimichi Fujiwara

Volume
264
Number
First page
107
Last page
115
Language
English
Publishing type
Research paper (scientific journal)
DOI
10.1016/j.jmr.2016.01.022

Sensitivity enhancement of MAS NMR using dynamic nuclear polarization (DNP) is gaining importance at moderate fields (B0<9T) and temperatures (T>90K) with potential applications in chemistry and material sciences. However, considering the ever-increasing size and complexity of the systems to be studied, it is crucial to establish DNP under higher field conditions, where the spectral resolution and the basic NMR sensitivity tend to improve. In this perspective, we overview our recent efforts on hardware developments, specifically targeted on improving DNP MAS NMR at high fields. It includes the development of gyrotrons that enable continuous frequency tuning and rapid frequency modulation for our 395 GHz-600 MHz and 460 GHz-700 MHz DNP NMR spectrometers. The latter 700 MHz system involves two gyrotrons and a quasi-optical transmission system that combines two independent sub-millimeter waves into a single dichromic wave. We also describe two cryogenic MAS NMR probe systems operating, respectively, at T ∼ 100K and ∼ 30K. The latter system utilizes a novel closed-loop helium recirculation mechanism, achieving cryogenic MAS without consuming any cryogen. These instruments altogether should promote high-field DNP toward more efficient, reliable and affordable technology. Some experimental DNP results obtained with these instruments are presented.

Link information
DOI
https://doi.org/10.1016/j.jmr.2016.01.022
PubMed
https://www.ncbi.nlm.nih.gov/pubmed/26920836
ID information
  • DOI : 10.1016/j.jmr.2016.01.022
  • ISSN : 1090-7807
  • Pubmed ID : 26920836

Export
BibTeX RIS