2017年6月
Design of a Rubbery Carboxymethyl Cellulose/Polyacrylic Acid Hydrogel via Visible-Light-Triggered Polymerization
MACROMOLECULAR MATERIALS AND ENGINEERING
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- 巻
- 302
- 号
- 6
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/mame.201600509
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
Hydrogels, as soft and wet materials, have attracted great attention in the field of functional biomaterials. Most recently, the designed hydrogels, according to the energy dissipation principle, overcome the low mechanical strength, poor toughness, and limited recoverability of common hydrogels and show excellent mechanical properties. However, most of these novel designed hydrogels are lacking of instantaneous recovery and antifatigue properties. In this study, a mesoscopic inhomogeneous hydrogel consisting of carboxymethyl cellulose and poly acrylic acid is synthesized through a facile, one-pot, visible-light-triggered polymerization. The prepared hydrogel can be stretched over 700% with fracture strength as high as 850 kPa, and shows a high elastic modulus (180 kPa). The microgel aggregated structure endows an efficient energy dissipation mechanism to the hydrogel. After the internal network structure stabilizing, the hydrogel exhibits a recovery time within 10 ms and over 92% resilience during impact and cyclic tensile tests, respectively. The hydrogel with such excellent mechanical properties can extend its application in biomaterial fields.
- リンク情報
- ID情報
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- DOI : 10.1002/mame.201600509
- ISSN : 1438-7492
- eISSN : 1439-2054
- Web of Science ID : WOS:000404200400008