論文

査読有り
2017年6月

Design of a Rubbery Carboxymethyl Cellulose/Polyacrylic Acid Hydrogel via Visible-Light-Triggered Polymerization

MACROMOLECULAR MATERIALS AND ENGINEERING
  • Longxiang Zhu
  • ,
  • Jianhui Qiu
  • ,
  • Eiichi Sakai
  • ,
  • Limin Zang
  • ,
  • Yanling Yu
  • ,
  • Kazushi Ito
  • ,
  • Peng Liu
  • ,
  • Feiyu Kang

302
6
記述言語
英語
掲載種別
研究論文(学術雑誌)
DOI
10.1002/mame.201600509
出版者・発行元
WILEY-V C H VERLAG GMBH

Hydrogels, as soft and wet materials, have attracted great attention in the field of functional biomaterials. Most recently, the designed hydrogels, according to the energy dissipation principle, overcome the low mechanical strength, poor toughness, and limited recoverability of common hydrogels and show excellent mechanical properties. However, most of these novel designed hydrogels are lacking of instantaneous recovery and antifatigue properties. In this study, a mesoscopic inhomogeneous hydrogel consisting of carboxymethyl cellulose and poly acrylic acid is synthesized through a facile, one-pot, visible-light-triggered polymerization. The prepared hydrogel can be stretched over 700% with fracture strength as high as 850 kPa, and shows a high elastic modulus (180 kPa). The microgel aggregated structure endows an efficient energy dissipation mechanism to the hydrogel. After the internal network structure stabilizing, the hydrogel exhibits a recovery time within 10 ms and over 92% resilience during impact and cyclic tensile tests, respectively. The hydrogel with such excellent mechanical properties can extend its application in biomaterial fields.

リンク情報
DOI
https://doi.org/10.1002/mame.201600509
Web of Science
https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000404200400008&DestApp=WOS_CPL
ID情報
  • DOI : 10.1002/mame.201600509
  • ISSN : 1438-7492
  • eISSN : 1439-2054
  • Web of Science ID : WOS:000404200400008

エクスポート
BibTeX RIS