2017年4月
Efficient synthesis of syn-α-alkoxy epoxide via a diastereoselective Darzens reaction
Tetrahedron
- ,
- ,
- ,
- 巻
- 73
- 号
- 15
- 開始ページ
- 2062
- 終了ページ
- 2067
- 記述言語
- 英語
- 掲載種別
- 研究論文（学術雑誌）
- DOI
- 10.1016/j.tet.2017.02.051
© 2017 Elsevier Ltd A highly diastereoselective Darzens reaction was developed by using a MEM- or TBDPS-protected α-hydroxy aldehyde with di-tert-butyl bromomalonate. This method effectively provides a syn-α-alkoxy epoxide, and a possible reaction mechanism was proposed to explain the high syn selectivity.
- リンク情報
-
- DOI
- https://doi.org/10.1016/j.tet.2017.02.051
- Web of Science
- https://gateway.webofknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=JSTA_CEL&SrcApp=J_Gate_JST&DestLinkType=FullRecord&KeyUT=WOS:000397694900009&DestApp=WOS_CPL
- URL
- https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=85014349147&origin=inward
- ID情報
-
- DOI : 10.1016/j.tet.2017.02.051
- ISSN : 0040-4020
- SCOPUS ID : 85014349147
- Web of Science ID : WOS:000397694900009