2015年12月
The Revised Structure of Trichodermatide A
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
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- 巻
- 号
- 35
- 開始ページ
- 7670
- 終了ページ
- 7673
- 記述言語
- 英語
- 掲載種別
- 研究論文(学術雑誌)
- DOI
- 10.1002/ejoc.201501281
- 出版者・発行元
- WILEY-V C H VERLAG GMBH
A revised structure for trichodermatide A, which is a C10 epimer of the originally reported structure, is proposed. The revision is supported by the X-ray structure of a synthetic intermediate synthesized according to our previous route for trichodermatide A. The revised stereochemistry was also supported by NOESY experiment. Finally, we synthesized Trauner's compound corresponding to the originally reported structure from our synthetic intermediate of trichodermatide A through a Mitsunobu reaction at C10.
- リンク情報
- ID情報
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- DOI : 10.1002/ejoc.201501281
- ISSN : 1434-193X
- eISSN : 1099-0690
- Web of Science ID : WOS:000366426600008